FMODB

FMODB: The database of quantum mechanical data based on the FMO method

Last updated: 2025-04-23

All entries: 37539

Number of unique PDB entries: 7791

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FMODB ID: 3Q9NL

Calculation Name: 4FKQ-AB-MD334-md1_12ns

Preferred Name: Cyclin-dependent kinase 2

Target Type: SINGLE PROTEIN

Ligand Name: 4-[(2z)-2-(7-oxidanylidene-3,6-dihydropyrrolo[3,2-e]benzotriazol-8-ylidene)hydrazinyl]benzenesulfonamide

ligand 3-letter code: 42K

PDB ID: 4FKQ

Chain ID: AB

ChEMBL ID: CHEMBL301

UniProt ID: P24941

Base Structure: MD

Registration Date: 2022-08-10

Reference: K. Takaba et al., Protein-ligand binding affinity prediction of cyclin-dependent kinase-2 inhibitors by dynamically averaged fragment molecular orbital-based interaction energy, J. Comput. Chem., 43, 1362-1371, 2022.

DOI: 10.1002/jcc.26940

Apendix: None


IFIE MAP

IFIE Diagram


Modeling method
Optimization MOE:Amber10:EHT
Restraint OptHLSolv
Protonation BaseStructure_original
Complement BaseStructure_original
Water Water molecules within 6 angstrom of a protein-ligand complex.
Procedure Manual calculation
FMO calculation
FMO method FMO2-MP2/6-31G(d)
Fragmentation Auto
Number of fragment 2679
LigandResidueName LIG
LigandFragmentNumber 299
LigandCharge
Software MIZUHO/ABINIT-MP 4.0
Total energy (hartree)
FMO2-HF: Electronic energy -18760167.146598
FMO2-HF: Nuclear repulsion 18460163.314285
FMO2-HF: Total energy -300003.832314
FMO2-MP2: Total energy -300824.686357


3D Structure
Snapshot
 
Ligand structure

LIG

ligand structure
Ligand Interaction
ligand interaction
Ligand binding energy (frag 299 : frag 1-298)
IFIE [kcal/mol] PIEDA [kcal/mol] Charge transfer value [e]
IFIE SUMIFIE SUM at MP2 level. ESElectro static interaction energy. EXExchange-repulsion energy. CT+mixCharge transfer and mixing terms energy. DI(MP2)Dispersion energy. q(I=>J)Charge transfer value from I to J fragments.
-118.112959-101.69309486.435347-39.142192-63.7130210.163392


Interactive mode: IFIE and PIEDA for fragment #299(A:299:LIG)


Summations of interaction energy for fragment #299(A:299:LIG)
IFIE [kcal/mol] PIEDA [kcal/mol] Charge transfer value [e]
IFIE SUMIFIE SUM at MP2 level. ESElectro static interaction energy. EXExchange-repulsion energy. CT+mixCharge transfer and mixing terms energy. DI(MP2)Dispersion energy. q(I=>J)Charge transfer value from I to J fragments.
-173.885-182.186166.61-72.012-86.305-0.104
Interaction energy analysis for fragmet #299(A:299:LIG)
Snapshot

IFIE Diagram

Base fragment(s) of PIEDA/IFIE
Single fragment Multi fragments
Fragment list
Charge [e] FCHARGE : 0 / q_Mulliken : -0.102 / q_NPA : ******
Distance from base fragment(s) [Å]
Dist
Interaction energy by IFIE and PIEDA
[kcal/mol]
| Total | > | ES | > | EX | >
| CT+mix | > | DI(MP2) | >
Fragment charge [e]
FCHARGE q_Mulliken
q_NPA q(I=>J)
Residue
Res #    RES   
Sort
Graph Options
X Axis Label
Y Axis Max Y Axis Min
Display   
frag_NumFragment number. ChainChain species. Res #Residue number. RES3-letter code of amino acid residue, ligand and solvent molecule. FCHARGEFormal charge [e]. q_MullikenFragment charge evaluated by Mulliken charge [e]. q_NPAFragment charge evaluated by natural population analysis(NPA) charge [e]. DISTDistance from Ligand [Å]. TotalIFIE at MP2 level [kcal/mol]. ESElectro static interaction energy by PIEDA [kcal/mol]. EXExchange-repulsion energy by PIEDA [kcal/mol]. CT+mixCharge transfer and mixing terms energy by PIEDA [kcal/mol]. DI(MP2)Dispersion energy by PIEDA [kcal/mol]. q(I=>J)Charge transfer value from I to J fragmens [e].
1A1MET10.77513.5580.2790.2790.0000.0000.0000.000
2A2GLU-1-0.57316.748-0.379-0.3790.0000.0000.0000.000
3A3ASN00.06114.9040.2530.2530.0000.0000.0000.000
4A4PHE00.04011.104-0.147-0.1470.0000.0000.0000.000
5A5GLN00.05212.6210.0150.0150.0000.0000.0000.000
6A6LYS10.90211.894-0.835-0.8350.0000.0000.0000.000
7A7VAL00.00410.366-0.043-0.0430.0000.0000.0000.000
8A8GLU-1-0.6668.1914.9684.9680.0000.0000.0000.000
9A9LYS10.8646.798-6.327-6.3270.0000.0000.0000.000
10A10ILE0-0.0312.818-4.5110.2122.030-1.302-5.4510.009
11A11GLY00.0223.2210.4212.2671.047-0.882-2.011-0.006
12A12GLU-1-0.6185.2430.9481.121-0.001-0.013-0.1590.000
13A13GLY0-0.0016.7030.8910.8910.0000.0000.0000.000
14A14THR0-0.0597.629-0.501-0.5010.0000.0000.0000.000
15A15TYR0-0.0305.9540.1700.1700.0000.0000.0000.000
16A16GLY00.0578.142-0.082-0.0820.0000.0000.0000.000
17A17VAL0-0.0567.9800.7240.7240.0000.0000.0000.000
18A18VAL00.0183.418-3.934-2.0910.182-0.472-1.5530.004
19A19TYR00.0116.7242.1152.1150.0000.0000.0000.000
20A20LYS10.8756.077-2.979-2.9790.0000.0000.0000.000
21A21ALA0-0.0217.1540.1980.1980.0000.0000.0000.000
22A22ARG10.8869.426-0.179-0.1790.0000.0000.0000.000
23A23ASN0-0.01511.7900.2140.2140.0000.0000.0000.000
24A24LYS10.85113.2950.2240.2240.0000.0000.0000.000
25A25LEU00.02016.5690.1170.1170.0000.0000.0000.000
26A26THR0-0.03814.5420.1070.1070.0000.0000.0000.000
27A27GLY00.08515.6250.0510.0510.0000.0000.0000.000
28A28GLU-1-0.7079.948-1.939-1.9390.0000.0000.0000.000
29A29VAL0-0.0267.059-0.066-0.0660.0000.0000.0000.000
30A30VAL0-0.0175.603-0.453-0.4530.0000.0000.0000.000
31A31ALA0-0.0162.8130.3951.8090.721-0.522-1.6140.003
32A32LEU00.0084.650-1.203-0.979-0.001-0.013-0.2110.000
33A33LYS10.8132.9188.0399.6280.133-0.502-1.2190.001
34A34LYS10.7796.826-0.736-0.7360.0000.0000.0000.000
35A35ILE00.0216.562-0.171-0.1710.0000.0000.0000.000
36A36ARG10.82310.188-0.049-0.0490.0000.0000.0000.000
37A37LEU00.03013.305-0.225-0.2250.0000.0000.0000.000
38A38ASP-1-0.62616.161-0.246-0.2460.0000.0000.0000.000
39A39THR00.02419.0510.1130.1130.0000.0000.0000.000
40A40GLU-1-0.69520.049-0.416-0.4160.0000.0000.0000.000
41A41THR00.12221.9730.0570.0570.0000.0000.0000.000
42A42GLU-1-0.67324.085-0.433-0.4330.0000.0000.0000.000
43A43GLY00.04823.1840.0160.0160.0000.0000.0000.000
44A44VAL00.04418.515-0.009-0.0090.0000.0000.0000.000
45A45PRO00.03815.8520.0500.0500.0000.0000.0000.000
46A46SER00.00617.604-0.158-0.1580.0000.0000.0000.000
47A47THR0-0.02816.821-0.076-0.0760.0000.0000.0000.000
48A48ALA00.02013.152-0.099-0.0990.0000.0000.0000.000
49A49ILE0-0.03413.679-0.309-0.3090.0000.0000.0000.000
50A50ARG10.86215.8961.0101.0100.0000.0000.0000.000
51A51GLU-1-0.73213.018-2.618-2.6180.0000.0000.0000.000
52A52ILE00.02310.806-0.312-0.3120.0000.0000.0000.000
53A53SER00.00912.797-0.159-0.1590.0000.0000.0000.000
54A54LEU00.02914.156-0.062-0.0620.0000.0000.0000.000
55A55LEU00.0178.198-0.044-0.0440.0000.0000.0000.000
56A56LYS10.7849.8901.7251.7250.0000.0000.0000.000
57A57GLU-1-0.65011.523-1.717-1.7170.0000.0000.0000.000
58A58LEU0-0.0339.5780.2660.2660.0000.0000.0000.000
59A59ASN0-0.01710.608-0.652-0.6520.0000.0000.0000.000
60A60HIS00.07311.4800.2200.2200.0000.0000.0000.000
61A61PRO00.00711.305-0.470-0.4700.0000.0000.0000.000
62A62ASN00.00011.5840.0090.0090.0000.0000.0000.000
63A63ILE0-0.0347.3480.0170.0170.0000.0000.0000.000
64A64VAL00.0442.622-1.603-0.3271.359-0.470-2.1650.001
65A65LYS10.7883.814-0.0170.5680.005-0.137-0.453-0.001
66A66LEU0-0.0154.636-2.088-1.949-0.001-0.019-0.1190.000
67A67LEU00.0466.2641.2841.2840.0000.0000.0000.000
68A68ASP-1-0.6678.740-1.134-1.1340.0000.0000.0000.000
69A69VAL00.0519.686-0.635-0.6350.0000.0000.0000.000
70A70ILE0-0.03612.1710.3830.3830.0000.0000.0000.000
71A71HIS00.01414.068-0.107-0.1070.0000.0000.0000.000
72A72THR00.07016.7010.1030.1030.0000.0000.0000.000
73A73GLU-1-0.67518.4620.0820.0820.0000.0000.0000.000
74A74ASN00.05719.9980.0800.0800.0000.0000.0000.000
75A75LYS10.74215.9940.0770.0770.0000.0000.0000.000
76A76LEU00.00311.788-0.072-0.0720.0000.0000.0000.000
77A77TYR0-0.00210.6200.0280.0280.0000.0000.0000.000
78A78LEU00.0256.426-0.142-0.1420.0000.0000.0000.000
79A79VAL00.0006.939-0.008-0.0080.0000.0000.0000.000
80A80PHE00.0172.051-6.207-3.2454.178-2.148-4.992-0.018
81A81GLU-1-0.6784.105-4.306-3.1020.001-0.600-0.605-0.002
82A82PHE00.0511.774-23.099-22.93313.503-7.159-6.509-0.046
83A83LEU0-0.0011.762-4.363-11.42214.332-3.902-3.3700.026
84A84HIS00.0462.179-11.389-8.4223.164-2.271-3.860-0.026
85A85GLN0-0.0013.007-3.586-0.3421.075-1.352-2.967-0.003
86A86ASP-1-0.6641.669-21.690-27.46619.025-6.262-6.987-0.052
87A87LEU00.0414.383-0.536-0.1810.003-0.065-0.2940.000
88A88LYS10.8955.458-2.061-2.0610.0000.0000.0000.000
89A89LYS10.8012.203-0.998-0.0591.940-0.858-2.022-0.003
90A90PHE00.0504.2291.3651.5320.000-0.055-0.1130.000
91A91MET0-0.0097.3140.4090.4090.0000.0000.0000.000
92A92ASP-1-0.6807.0711.2951.2950.0000.0000.0000.000
93A93ALA0-0.0188.0010.2240.2240.0000.0000.0000.000
94A94SER00.0139.6700.0630.0630.0000.0000.0000.000
95A95ALA0-0.02912.749-0.009-0.0090.0000.0000.0000.000
96A96LEU00.00614.5830.0110.0110.0000.0000.0000.000
97A97THR0-0.03117.313-0.040-0.0400.0000.0000.0000.000
98A98GLY00.10517.123-0.022-0.0220.0000.0000.0000.000
99A99ILE00.00212.613-0.010-0.0100.0000.0000.0000.000
100A100PRO00.05416.820-0.004-0.0040.0000.0000.0000.000
101A101LEU00.02219.394-0.054-0.0540.0000.0000.0000.000
102A102PRO00.00421.262-0.055-0.0550.0000.0000.0000.000
103A103LEU00.03114.381-0.052-0.0520.0000.0000.0000.000
104A104ILE0-0.00817.131-0.085-0.0850.0000.0000.0000.000
105A105LYS10.84118.3600.2630.2630.0000.0000.0000.000
106A106SER00.01018.889-0.088-0.0880.0000.0000.0000.000
107A107TYR00.00011.374-0.105-0.1050.0000.0000.0000.000
108A108LEU00.01416.423-0.123-0.1230.0000.0000.0000.000
109A109PHE0-0.01018.382-0.095-0.0950.0000.0000.0000.000
110A110GLN00.00714.991-0.163-0.1630.0000.0000.0000.000
111A111LEU00.02911.965-0.193-0.1930.0000.0000.0000.000
112A112LEU00.00715.259-0.176-0.1760.0000.0000.0000.000
113A113GLN00.01017.101-0.091-0.0910.0000.0000.0000.000
114A114GLY00.01813.454-0.048-0.0480.0000.0000.0000.000
115A115LEU00.01314.116-0.169-0.1690.0000.0000.0000.000
116A116ALA0-0.00115.161-0.002-0.0020.0000.0000.0000.000
117A117PHE00.02614.1780.0140.0140.0000.0000.0000.000
118A118CYS0-0.03312.044-0.196-0.1960.0000.0000.0000.000
119A119HIS00.01714.5170.1270.1270.0000.0000.0000.000
120A120SER00.01017.5610.1170.1170.0000.0000.0000.000
121A121HIS0-0.01914.0240.2410.2410.0000.0000.0000.000
122A122ARG10.81816.9231.0941.0940.0000.0000.0000.000
123A123VAL0-0.00112.108-0.026-0.0260.0000.0000.0000.000
124A124LEU00.05014.0690.1010.1010.0000.0000.0000.000
125A125HIS0-0.0146.074-0.154-0.1540.0000.0000.0000.000
126A126ARG10.84910.0021.4071.4070.0000.0000.0000.000
127A127ASP-1-0.6677.517-0.940-0.9400.0000.0000.0000.000
128A128LEU00.0028.4290.1890.1890.0000.0000.0000.000
129A129LYS10.8436.813-0.136-0.1360.0000.0000.0000.000
130A130PRO00.0248.2800.0360.0360.0000.0000.0000.000
131A131GLN00.0345.169-1.161-1.1610.0000.0000.0000.000
132A132ASN0-0.0433.8363.3884.6120.031-0.340-0.9150.001
133A133LEU00.0134.686-2.312-2.0260.000-0.020-0.2670.000
134A134LEU00.0102.673-4.356-1.9587.170-1.757-7.8110.006
135A135ILE0-0.0436.1320.0260.0260.0000.0000.0000.000
136A136ASN00.0097.2040.1470.1470.0000.0000.0000.000
137A137THR00.0589.874-0.053-0.0530.0000.0000.0000.000
138A138GLU-1-0.67312.631-0.765-0.7650.0000.0000.0000.000
139A139GLY00.06514.6690.0070.0070.0000.0000.0000.000
140A140ALA0-0.02512.473-0.026-0.0260.0000.0000.0000.000
141A141ILE0-0.01110.3010.0090.0090.0000.0000.0000.000
142A142LYS10.7907.9862.3022.3020.0000.0000.0000.000
143A143LEU00.0258.6160.2750.2750.0000.0000.0000.000
144A144ALA00.0673.304-2.266-0.7790.381-0.462-1.4050.004
145A145ASP-1-0.7331.714-35.182-37.57316.118-7.500-6.226-0.062
146A146PHE00.0953.5162.8433.1550.040-0.041-0.3110.000
147A147GLY0-0.0116.817-0.913-0.9130.0000.0000.0000.000
148A148LEU0-0.0104.4690.6770.799-0.001-0.018-0.1030.000
149A149ALA00.0488.0760.7600.7600.0000.0000.0000.000
150A150ARG10.8599.8992.5132.5130.0000.0000.0000.000
151A151ALA0-0.02112.4540.3620.3620.0000.0000.0000.000
152A152PHE00.01910.1020.2500.2500.0000.0000.0000.000
153A153GLY00.03913.8440.2680.2680.0000.0000.0000.000
154A154VAL0-0.04713.545-0.129-0.1290.0000.0000.0000.000
155A155PRO00.02514.7930.1420.1420.0000.0000.0000.000
156A156VAL00.02815.9520.0040.0040.0000.0000.0000.000
157A157ARG10.81516.753-0.188-0.1880.0000.0000.0000.000
158A158THR00.00812.549-0.129-0.1290.0000.0000.0000.000
159A159TYR00.04115.0960.0080.0080.0000.0000.0000.000
160A160THR0-0.05615.437-0.023-0.0230.0000.0000.0000.000
161A161HIS00.05817.7510.1440.1440.0000.0000.0000.000
162A162GLU-1-0.65714.9351.4591.4590.0000.0000.0000.000
163A163VAL00.03215.816-0.115-0.1150.0000.0000.0000.000
164A164VAL00.00412.0230.2530.2530.0000.0000.0000.000
165A165THR0-0.00714.131-0.175-0.1750.0000.0000.0000.000
166A166LEU00.01514.791-0.104-0.1040.0000.0000.0000.000
167A167TRP00.00213.883-0.101-0.1010.0000.0000.0000.000
168A168TYR00.00112.413-0.090-0.0900.0000.0000.0000.000
169A169ARG10.84313.9110.2680.2680.0000.0000.0000.000
170A170ALA0-0.00317.8750.0650.0650.0000.0000.0000.000
171A171PRO00.05620.5750.0030.0030.0000.0000.0000.000
172A172GLU-1-0.71221.674-0.549-0.5490.0000.0000.0000.000
173A173ILE0-0.02617.1250.0100.0100.0000.0000.0000.000
174A174LEU0-0.00520.7640.0460.0460.0000.0000.0000.000
175A175LEU00.01623.4280.0500.0500.0000.0000.0000.000
176A176GLY00.07724.0830.0030.0030.0000.0000.0000.000
177A177CYS0-0.07723.002-0.034-0.0340.0000.0000.0000.000
178A178LYS10.87721.2630.5410.5410.0000.0000.0000.000
179A179TYR0-0.01821.561-0.101-0.1010.0000.0000.0000.000
180A180TYR00.05816.941-0.009-0.0090.0000.0000.0000.000
181A181SER00.05520.960-0.064-0.0640.0000.0000.0000.000
182A182THR00.06018.015-0.008-0.0080.0000.0000.0000.000
183A183ALA0-0.01918.672-0.013-0.0130.0000.0000.0000.000
184A184VAL00.00515.6400.0720.0720.0000.0000.0000.000
185A185ASP-1-0.71113.458-1.675-1.6750.0000.0000.0000.000
186A186ILE0-0.04215.6820.0110.0110.0000.0000.0000.000
187A187TRP00.04518.8340.0390.0390.0000.0000.0000.000
188A188SER00.02013.9870.0130.0130.0000.0000.0000.000
189A189LEU0-0.00114.8780.0850.0850.0000.0000.0000.000
190A190GLY00.03016.2470.0650.0650.0000.0000.0000.000
191A191CYS0-0.11216.9160.0780.0780.0000.0000.0000.000
192A192ILE00.05611.9530.0840.0840.0000.0000.0000.000
193A193PHE0-0.04015.9400.0230.0230.0000.0000.0000.000
194A194ALA00.05518.7130.0320.0320.0000.0000.0000.000
195A195GLU-1-0.67714.3230.3440.3440.0000.0000.0000.000
196A196MET0-0.00813.6250.0190.0190.0000.0000.0000.000
197A197VAL00.00415.7500.0070.0070.0000.0000.0000.000
198A198THR0-0.02618.6840.0510.0510.0000.0000.0000.000
199A199ARG10.84014.973-0.126-0.1260.0000.0000.0000.000
200A200ARG10.85316.701-0.047-0.0470.0000.0000.0000.000
201A201ALA00.01618.440-0.060-0.0600.0000.0000.0000.000
202A202LEU00.00919.289-0.011-0.0110.0000.0000.0000.000
203A203PHE00.00521.558-0.005-0.0050.0000.0000.0000.000
204A204PRO00.05921.3580.0060.0060.0000.0000.0000.000
205A205GLY00.09922.011-0.060-0.0600.0000.0000.0000.000
206A206ASP-1-0.70221.9140.5880.5880.0000.0000.0000.000
207A207SER00.00323.2110.0250.0250.0000.0000.0000.000
208A208GLU-1-0.63522.015-0.204-0.2040.0000.0000.0000.000
209A209ILE0-0.01924.106-0.040-0.0400.0000.0000.0000.000
210A210ASP-1-0.73026.2630.1470.1470.0000.0000.0000.000
211A211GLN0-0.01721.1550.0550.0550.0000.0000.0000.000
212A212LEU00.01324.292-0.029-0.0290.0000.0000.0000.000
213A213PHE00.03326.470-0.011-0.0110.0000.0000.0000.000
214A214ARG10.81626.037-0.130-0.1300.0000.0000.0000.000
215A215ILE00.01223.718-0.011-0.0110.0000.0000.0000.000
216A216PHE00.04327.733-0.010-0.0100.0000.0000.0000.000
217A217ARG10.83331.286-0.038-0.0380.0000.0000.0000.000
218A218THR0-0.02128.5580.0250.0250.0000.0000.0000.000
219A219LEU0-0.05927.216-0.008-0.0080.0000.0000.0000.000
220A220GLY00.05731.461-0.021-0.0210.0000.0000.0000.000
221A221THR0-0.02632.751-0.013-0.0130.0000.0000.0000.000
222A222PRO00.02330.348-0.008-0.0080.0000.0000.0000.000
223A223ASP-1-0.64833.360-0.169-0.1690.0000.0000.0000.000
224A224GLU-1-0.61535.249-0.259-0.2590.0000.0000.0000.000
225A225VAL00.00636.676-0.017-0.0170.0000.0000.0000.000
226A226VAL00.03733.508-0.006-0.0060.0000.0000.0000.000
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